碳酸盐

Multi tool use
碳酸盐是指含CO32-的盐。碳酸盐遇酸能发生复分解反应产生CO2(碱式碳酸盐还能产生水),实验室通常利用这一原理检验某固体含碳酸盐及制取CO2。碳酸盐通常不如其他常见盐(如硫酸盐,卤盐)稳定,仅活泼金属(全部碱金属及钡,锶等)的碳酸盐不易分解,其余盐加热未到熔沸点便已分解,金属越不活泼分解温度越低,产物为对应金属氧化物及CO2。
碳酸盐的种类
正盐:其中阳离子全为金属离子或NH+
4,不含H+的盐。如:CaCO3,(NH4)2CO3等。
酸式碳酸盐:阳离子含H+的盐,读作“碳酸氢某”。如:NaHCO3,NH4HCO3等。
通常,碳酸盐溶液中通入CO2得酸式碳酸盐;甚至微溶的碳酸盐在水中通入CO2,也将转化为可溶性的酸式碳酸盐。例如:碳酸钙在水中通入CO2即转化为酸式碳酸钙而溶解;酸式碳酸盐也叫碳酸氢盐或重碳酸盐;加热即放出CO2而成碳酸正盐,加热到更高温度进一步分解为对应金属氧化物及CO2。
- 碱式碳酸盐:阴离子含OH−的碳酸盐,读作“碱式碳酸某”。如Cu2(OH)2CO3、碱式碳酸铅等,也可以当作是另一类型的碳酸盐。
常见的碳酸盐
碳酸钠(NaCO3),俗称纯碱或者苏打。
碳酸钙(CaCO3),俗称白堊或石灰石或者大理石。
无机碳化合物
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氧化物及相关 |
氧化物
- CO2
- CO
- CO3
- CO4
- C2O
- C2O2
- C3O2
- C4O2
- C5O2
- OCS
- 金属羰基配合物
- 碳酸
- 碳酸氢盐
- 碳酸盐
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其他离子化合物 |
碳化物 [:C≡C:]2–, [::C::]4–, [:C=C=C:]4–
氰化物 [:C≡N:]–
氰酸盐 [:O-C≡N:]–
硫氰酸盐 [:S-C≡N:]–
雷酸盐 [:C≡N-O:]–
异硫氰酸盐 [:C≡N-S:]–
- 石墨层间化合物
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其他共价化合物 |
- CF
- CF4
- CCl4
- CBr4
- CI4
- CS
- CS2
- C3S2
- CSe2
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